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SDS of Cerium or Ceric Ammonium Nitrate Manufacturers
CAS Number 16774-21-3
Cerium or Ceric Ammonium Nitrate Manufacturers.
Ceric Ammonium Nitrate or Cerium Ammonium Nitrate SDS, Safety Data Sheet
MSDS, Material Safety Data Sheet 31-Aug-22
1. Product Identification
Product Name & Other Names: Ceric Ammonium Nitrate or CAN or Ammonium Hexanitratocerate (IV) or Diammonium Hexanitratocerate or Hexanitrato Ammoniumcerate or Ammonium Cerium Nitrate.
CAS No.: 16774-21-3
EINECS: EC Number: 240-827-6
Molecular Weight: 548.23
Chemical Formula: (NH4)2Ce(NO3)6
Relevant uses and uses advised against (if any): Industrial Manufacturing.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Oxidizing liquids; Oxidizing solids Category 3, H272
Acute toxicity, oral Category 4, H302
Skin corrosion/irritation Category 1A, B, C, H314
Skin corrosion/irritation Category 2, H315
Serious eye damage/eye irritation Category 2A, H319
Specific target organ toxicity, single exposure; Respiratory tract irritation Category 3, H335
Labeling according Regulation (EC) No 1272/2008
GHS Label Elements  Oxidizing Solid |
|
Signal Word: Danger
Hazard Statements:
H272: May intensify fire; oxidizer.
H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
Precautionary Statements:
P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P220: Keep/Store away from clothing/other combustible materials.
P221: Take any precaution to avoid mixing with combustibles.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash --- thoroughly after handling.
P270: Do not eat, drink, or smoke when using this product.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth.
P301+330+331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P362: Take off contaminated clothing and wash before reuse.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P405: Store locked up.
P501: Dispose of contents/container to authorized agents only.
3. Composition/Information on Ingredients
Product Name & Other Names: Ceric Ammonium Nitrate or CAN or Ammonium Hexanitratocerate (IV) or Diammonium Hexanitratocerate or Hexanitrato Ammoniumcerate or Ammonium Cerium Nitrate.
CAS No.: 16774-21-3
EINECS: EC Number: 240-827-6
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician: Symptomatic and supportive treatment is recommended.
5. Fire Fighting Measures
Flammability of the Product: Non-flammable but it is an oxidizer.
Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: It emits toxic oxides of nitrogen when heated to decomposition.
Fire: It is supporting fire as an oxidizer.
Explosion: Contact with oxidizable substances may cause explosion.
Fire Extinguishing Media: Water spray. Use means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used.
6. Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Do not approach facing the wind.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow evacuating as per law.
7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like organic substances, metal powders, combustible and reducing agents.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
9. Physical and Chemical Properties
Appearance: Cerium ammonium nitrate is Orange Red or Orange Yellow crystals or powder or granules.
Odor: Slight.
Odor threshold: Not available.
pH: Not available.
Relative density: Not available.
Boiling Point: > 1600C (> 2912F)
Melting Point: 107C with decomposition for Ceric Ammonium Nitrate.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: 141g/100ml water @ 25C (77F).
Viscosity: Not available.
10. Stability and Reactivity
Stability: Cerium Ammonium Nitrate is stable under ordinary conditions of use and storage. Substance will pick up moisture from the air and go into solution if exposed in open containers.
Hazardous Decomposition Products: It emits toxic oxides of nitrogen when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Organic substances, Metal powders, Combustible and Reducing agents.
Conditions to Avoid: Incompatibles.
11. Toxicological Information
Toxicity to Animals: LD50: Not available. LC50: Not available.
Special Remarks on Toxicity to Animals: Not available.
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
12. Ecological Information
BOD5 and COD: Not available.
Environmental Fate: No information found.
Environmental Toxicity: The material is not considered as environmental hazard.
Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations.
14. Transport Information
DOT USA, TDG Canada & ADR/RID Europe:
UN number: 1477 Class: 5.1 Oxidizing material. Packing group: II
Proper shipping name: Nitrates, inorganic, n.o.s.
IMDG/IMO:
UN number: 1477 Class: 5.1 Packing group: II EMS-No: F-A, S-Q
Proper shipping name: NITRATES, INORGANIC, N.O.S.
IATA/ICAO:
UN number: 1477 Class: 5.1 Packing group: II
Proper shipping name: Nitrates, inorganic, n.o.s.
15. Regulatory Information
USA:
SARA 311/312 Hazards: Acute Health Hazard.
California Prop 65: California No Significant Risk Level: None of the chemicals in this product are listed.
Section 16 - Additional Information
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
Cerium or Ceric Ammonium Nitrate
Cerium or Ceric Ammonium Nitrate Manufacturers:
Muby Chemicals & Associated Cos
BANDEALI BUILDING, CHINCHBUNDER, MUMBAI 400009, INDIA.
TEL: 91-22-23728264. Gujarat & Mumbai India.
info(At the Rate i.e. @)mubychem(dot)com
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Last updated
31-aug-22
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