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SDS of Calcium Nitrite Pure AR Analytical Reagent Manufacturers,
CAS Number Calcium Nitrite 13780-06-8 & Calcium Nitrate 13477-34-4
Calcium Nitrite Manufacturers.
Calcium Nitrite Crystals SDS, Safety Data Sheet
MSDS, Material Safety Data Sheet 30-Aug-22
1. Product Identification
Product Name & Other Names: Calcium Nitrite or Calcium salt of nitrous acid or Calcium dinitrite or Daraset.
CAS No.: 13780-06-8
EINECS: EC Number: 237-424-2.
Molecular Weight: 132.09
Chemical Formula: Ca(NO2)2 ( Calcium Nitrite)
Relevant uses and uses advised against (if any): Industrial use only.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Oxidizing solids Category 3 H272
Acute toxicity - Oral Category 3 H301
Serious eye damage/eye irritation (Category 2A) H319
Hazardous to the aquatic environment, acute hazard Category 1 H402
Labeling according GHS USA & Regulation (EC) No 1272/2008
GHS Label Elements  Oxidizing Solid |
GHS Label Elements |
Signal Word: Warning
Hazard Statements:
H272: May intensify fire; oxidizer.
H301: Toxic if swallowed.
H319: Causes serious eye irritation.
H402: Harmful to aquatic life.
Precautionary Statements
P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P220: Keep/Store away from clothing/other combustible materials.
P221: Take any precaution to avoid mixing with combustibles.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash thoroughly after handling.
P273: Avoid release to the environment.
P270: Do not eat, drink or smoke when using this product.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth.
P362: Take off contaminated clothing and wash before reuse.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P501: Dispose of contents/container to authorized agents.
3. Composition/Information on Ingredients
Product Name & Other Names: Calcium Nitrite or Calcium salt of nitrous acid or Calcium dinitrite or Daraset.
CAS No.: 13780-06-8
EINECS: EC Number: 237-424-2.
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician: Symptomatic and supportive treatment is recommended.
5. Fire Fighting Measures
Flammability of the Product: Non-flammable. However the product supports combustion.
Products of Combustion: When heated to decomposition, emits acid fumes.
Fire: Not considered to be a fire hazard though it supports combustion as an oxidizer.
Explosion: Containers may explode in the heat of a fire.
Fire Extinguishing Media: Preferably use water sprat. Use any means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. Calcium Nitrite is a Strong Oxidizer. May decompose explosively when heated or involved in a fire. May accelerate burning if involved in a fire.
6. Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.
7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like reducing agents, organic materials, water.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
9. Physical and Chemical Properties
Appearance: White crystals or powder or granules.
Odor: It is odorless.
Odor threshold: Not available.
pH: Not available.
Relative density: around 2.26
Melting Point: 390C.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: It is freely soluble in water.
Viscosity: Not available.
10. Stability and Reactivity
Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits toxic acid fumes when heated to decomposition. Nitrogen oxides (NOx), Calcium oxide are formed.
Hazardous Polymerization: Will not occur.
Incompatibilities: Reactive with reducing agents, organic materials. The product may undergo hazardous decomposition, condensation, or polymerization, it may react violently with water to emit toxic gases or it may become self-reactive under conditions of shock or increase in temperature or pressure.
Conditions to Avoid: Incompatibles. Avoid contact with combustible material (paper, wool, oil).
11. Toxicological Information
Toxicity to Animals: LD50 (Oral-Rat) 940 mg/kg
Special Remarks on Toxicity to Animals: Not available.
Carcinogenic Effects: Not a reported carcinogen.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
12. Ecological Information
BOD5 and COD: Not available.
Environmental Toxicity: The product may be harmful to plants, animals and fish.
Persistence and Degradability: Unlikely to persist due to water solubility.
Mobility: Likely to be mobile due to water solubility.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations.
14. Transport Information
DOT USA, TDG Canada & ADR/RID Europe:
Proper Shipping Name: Nitrites, Inorganic, (Calcium Nitrite)
U.N. No.: 2627
Hazard Class and Packing Group Number: 5.1, PG II
Marine Pollutant: NO
IMDG/IMO & IATA/ICAO:
Proper Shipping Name: Nitrites, Inorganic, (Calcium Nitrite)
U.N. No.: 2627
Hazard Class and Packing Group Number: 5.1, PG II
Marine Pollutant: NO
15. Regulatory Information
USA:
Hazard Category: Immediate (Acute), Fire Hazard
US SARA Hazard categories (section 311/312, 40 CFR 370-21): Fire and Acute health hazard.
Section 16 - Additional Information
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
Calcium Nitrite
Calcium Nitrite Pure & ACS AR Analytical Reagent Grade Manufacturers:
Muby Chemicals & Associated Cos
BANDEALI BUILDING, CHINCHBUNDER, MUMBAI 400009, INDIA.
TEL: 91-22-23728264. Gujarat & Mumbai India.
info(At the Rate i.e. @)mubychem(dot)com
Copyright and Usual Disclaimer is Applicable
Last updated
30-aug-22
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