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SDS of Magnesium Sulphate Magnesium Sulfate USP FCC ACS AR Analytical Reagent FCC Food Grade Manufacturers

CAS Number heptahydrate 10034-99-8 & anhydrous 7487-88-9 monohydrate 14168-73-1

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Magnesium Sulfate Anhydrous & Dried SDS Safety Data Sheet
MSDS, Material Safety Data Sheet
03-Sept-22

1. Product Identification

Product Name & Other Names: Magnesium sulfate (1:1) anhydrous or dried, Sulfuric acid magnesium salt. Epsom salt.
CAS No.: 7487-88-9 Anhydrous (14168-73-1 is also cited)
EINECS: 231-298-2
Molecular Weight: 120.37 for Anhydrous.
Chemical Formula: MgSO4.xH2O. (x is generally up to 4)
Relevant uses and uses advised against (if any): Industrial Manufacturing.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.

Labeling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements
NONE

Signal Word: None

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.

3. Composition/Information on Ingredients

Product Name & Other Names: Magnesium sulfate (1:1) anhydrous or dried, Sulfuric acid magnesium salt. Epsom salt.
CAS No.: 7487-88-9
EINECS: 231-298-2

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion: Give several glasses of water to drink to dilute. If large amounts were swallowed, get medical advice.
Skin Contact: Remove any contaminated clothing. Wash skin with soap and water for at least 15 minutes. Get medical attention if irritation develops or persists.
Eye Contact: Wash thoroughly with running water. Get medical advice if irritation develops.
Note to Physician: IV administration of calcium gluconate will partially reverse the effects of acute magnesium toxicity. Ventricular support with calcium chloride infusion and mannitol forced diuresis has also been successful.

5. Fire Fighting Measures

Fire: Not flammable.
Special Information: Use protective clothing and breathing equipment appropriate for the surrounding fire.
Products of Combustion
: Sulphuric acid, Sulphur Dioxide and Magnesium Oxide may be formed.
Fire Extinguishing Media: Use means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used.

6. Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Do not approach facing the wind.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow evacuating through the sanitary system if local laws permit.

7. Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, ethoxy ethyl alcohols, arsenates, phosphates, tartrates, lead, barium, strontium, and calcium.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Magnesium Sulfate is white powder.
Odor: It is odorless.
Odor threshold: Not available.
pH: Aqueous solution is neutral or slightly acid.
Relative density: around 2.65
Melting Point: 1124C (2055F) Decomposes.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Very soluble in water.
Viscosity: Not available.

10. Stability and Reactivity

Stability: Stable under ordinary conditions of use and storage. Absorbs moisture on exposure.
Hazardous Decomposition Products: Oxides of sulfur and the contained metal.
Hazardous Polymerization: Will not occur.
Incompatibilities: Ethoxy ethyl alcohols, arsenates, phosphates, tartrates, lead, barium, strontium, and calcium.
Conditions to Avoid: Heat, moisture, incompatibles.

11. Toxicological Information

Toxicity to Animals:
LD50 Subcutaneous - mouse - 645 mg/kg
LD50 Subcutaneous - rat - 1.200 mg/kg
Carcinogenic Effects: Not a reported carcinogen by IARC NTP ACGIH OSHA.
Mutagenic Effects: Laboratory experiments have resulted in mutagenic effects.
Teratogenic Effects: No.

12. Ecological Information

Environmental Toxicity:
24 hour EC50 Daphnia magna (water flea) : 1700 mg/L.
24 hour LC50 Lepomis machrochirus (bluegill) : > 5000 mg/L [static].
72 hour EC50 Scenedesmus subspicatus (green algae) : 2700 mg/L.
This material is not expected to be toxic to aquatic life.
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility.

14. Transport Information

DOT USA, TDG Canada & ADR/RID Europe: Not controlled.
IMDG/IMO: Not controlled.
IATA/ICAO: Not controlled.

15. Regulatory Information

USA:
SARA Codes: CAS # 7487-88-9: acute.
California No Significant Risk Level: None of the chemicals in this product are listed.

Section 16 - Additional Information

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.


Magnesium Sulfate Heptahydrate or Magnesium Sulphate Heptahydrate SDS, Safety Data Sheet
MSDS, Material Safety Data Sheet
03-Sept-22

1. Product Identification

Product Name & Other Names: Magnesium sulphate heptahydrate or Magnesium sulfate (1:1) heptahydrate or Epsom salts or sulfuric acid magnesium salt (1:1) heptahydrate or Magnesium sulfate 7- hydrate.
CAS No.: 10034-99-8 Heptahydrate
EINECS: 231-298-2
Molecular Weight: 246.48
Chemical Formula: MgSO4-7H2O
Relevant uses and uses advised against (if any): Industrial Manufacturing.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.

Labeling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements
NONE

Signal Word: None

Precautionary Statements
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.

3. Composition/Information on Ingredients

Product Name & Other Names: Magnesium sulphate heptahydrate or Magnesium sulfate (1:1) heptahydrate or Epsom salts or sulfuric acid magnesium salt (1:1) heptahydrate or Magnesium sulfate 7- hydrate.
CAS No.: 10034-99-8 Heptahydrate
EINECS: 231-298-2

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion: Give several glasses of water to drink to dilute. If large amounts were swallowed, get medical advice.
Skin Contact: Remove any contaminated clothing. Wash skin with soap and water for at least 15 minutes. Get medical attention if irritation develops or persists.
Eye Contact: Wash thoroughly with running water. Get medical advice if irritation develops.
Note to Physician: IV administration of calcium gluconate will partially reverse the effects of acute magnesium toxicity. Ventricular support with calcium chloride infusion and mannitol forced diuresis has also been successful.

5. Fire Fighting Measures

Fire: Not flammable.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire.
Products of Combustion: Sulphuric acid, Sulphur Dioxide and Magnesium Oxide may be formed.
Fire Extinguishing Media: Use means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used.

6. Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).Do not approach facing the wind.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow evacuating through the sanitary system if local laws permit.

7. Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, ethoxy ethyl alcohols, arsenates, phosphates, tartrates, lead, barium, strontium, and calcium.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: White crystals or powder.
Odor: It is odorless.
Odor threshold: Not available.
pH: Aqueous solution is neutral or slightly acid.
Relative density: around 2.66
Melting Point: Loses water on heating.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Very soluble in water.
Viscosity: Not available.

10. Stability and Reactivity

Stability: Stable under ordinary conditions of use and storage. Absorbs moisture on exposure.
Hazardous Decomposition Products: Oxides of sulfur and the contained metal.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, Ethoxy ethyl alcohols, arsenates, phosphates, tartrates, lead, barium, strontium, and calcium.
Conditions to Avoid: Heat, moisture, incompatibles.

11. Toxicological Information

Toxicity to Animals:
D50 = No information found.
LC50 = No information found.
Carcinogenic Effects: No.
Mutagenic Effects: Laboratory experiments have resulted in mutagenic effects.
Teratogenic Effects: No.
Developmental Toxicity: Laboratory experiments have resulted in mutagenic effects.

12. Ecological Information

Environmental Toxicity:
24 hour EC50 Daphnia magna (water flea) : 1700 mg/L.
24 hour LC50 Lepomis machrochirus (bluegill) : > 5000 mg/L [static].
72 hour EC50 Scenedesmus subspicatus (green algae) : 2700 mg/L.
This material is not expected to be toxic to aquatic life.
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility.

14. Transport Information

DOT USA, TDG Canada & ADR/RID Europe: Not controlled.
IMDG/IMO: Not controlled.
IATA/ICAO: Not controlled.

15. Regulatory Information

USA:
SARA Codes: See section 2.
Section 313: No chemicals are reportable under Section 313.

Section 16 - Additional Information

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

Magnesium Sulfate Heptahydrate Manufacturers Magnesium Sulfate Monohydrate Dried Suppliers Magnesium Sulfate Anhydrous Exporters

Magnesium Sulphate Magnesium Sulfate USP ACS AR Analytical Reagent FCC Food Grade manufacturers

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TEL: 91-22-23728264. Gujarat & Mumbai India.

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Last updated 3-sep-22

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